Here are nice stops going to Bicol.
1. Atimonan - Sa taas, sa Quezon National Park.
2. Atimonan Pier
If you want to drop by Bagasbas Beach in Cams. Norte, use the old Maharlika Highway bypassing Quirino Highway that cuts the the old route to 30-45 munutes. Waves in this shorelines are very nice and captivating specially for Surfers.
In Cam. Sur, the CWC, in Albay, you can drop Hoyop-hoyopan Cave in Camalig, there's also a classic 100+ year old house in Libon which still exists and owned by Ayo family, where the likes of Aguinaldo and company met, during the Spanish era for their meetings. Century old utencils, cabinets, etc are there for private viewing only. The Cagsawa Ruins in Daraga. Misibis Resort in 1st district of Albay. The Mayon Volcano has a good view if you're on the side of Tabaco, Tiwi. The side facing Guinobatan, Ligao, Camalig is not so good.
Going farther South in Sorsogon, is Donsol known for its Butantig. These are only few of those good sites in Bicol.
*TS, BTW, changed your topic from Vulcano to Volcano

. No offense meant.