Lead
The mixture known as gasoline, when used in high
compression internal combustion engines, has a tendency to ignite early (
pre-ignition or
detonation) causing a damaging "
engine knocking" (also called "pinging" or "pinking") noise. Early research into this effect was led by A.H. Gibson and
Harry Ricardo in England and
Thomas Midgley and Thomas Boyd in the United States. The discovery that
lead additives modified this behavior led to the widespread adoption of the practice in the 1920s and therefore more powerful higher compression engines. The most popular additive was
tetra-ethyl lead. However, with the discovery of the environmental and health damage caused by the lead, and the incompatibility of lead with
catalytic converters found on virtually all automobiles since 1975, this practice began to wane in the 1980s. Most countries are phasing out leaded fuel; different additives have replaced the lead compounds.
The most popular additives include aromatic hydrocarbons, ethers and alcohol (usually ethanol or methanol).
In the U.S., where lead was blended with gasoline—primarily to boost octane levels—since the early 1920s, standards to phase out leaded gasoline were first implemented in 1973. In 1995, leaded fuel accounted for only 0.6 % of total gasoline sales and less than 2,000 tons of lead per year. From
January 1,
1996, the
Clean Air Act banned the sale of leaded fuel for use in on-road vehicles. Possession and use of leaded gasoline in a regular on-road vehicle now carries a maximum $10,000 fine in the United States. However, fuel containing lead may continue to be sold for off-road uses, including aircraft, racing cars, farm equipment, and marine engines until 2008. The ban on leaded gasoline led to thousands of tons of lead not being released in the air by automobiles, and resulted in lowering levels of lead in people's
bloodstreams.
A side effect of the lead additives was protection of the valve seats from erosion. Many classic cars' engines have needed modification to use lead-free fuels since leaded fuels became unavailable. However, "Lead substitute" products are also produced and can sometimes be found at auto parts stores.
Gasoline, as delivered at the pump, also contains additives to reduce internal engine carbon buildups, improve
combustion, and to allow easier starting in cold climates.
In most of
South America,
Africa, and some parts of
Asia and the
Middle East, leaded gasoline is common.