Here is a tutorial from JL Audio on how to properly set your amps gain controls. This is the best you can do short of having access to an oscilioscope (tama ba spelling?)
Only drawback with this method is you are setting your amp for the rated capacity. If your amp is underrated, you will miss out on some watts. But afaik, the only way properly set rest of the watts is with the use of an o-scope. If you have one you probably don't need this guide anyway.